174850-40-9

Upstream product

• 93173-26-3 2,3,4,6-Tetra-O-benzyl-α-D-glucopyranosyl isothiocyanate 
• 70128-27-7 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosylamine 

Downstream Products

• 181960-89-4 (3aS,5R,6S,7S,7aR)-5-Hydroxymethyl-2-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylamino)-5,6,7,7a-tetrahydro-3aH-pyrano[2,3-d]oxazole-6,7-diol 
• 181960-90-7 (R)-1-[(3aS,5R,6S,6aR)-6-Hydroxy-2-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylamino)-3a,5,6,6a-tetrahydro-furo[2,3-d]oxazol-5-yl]-ethane-1,2-diol 
• 174850-41-0 1-((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yl)-3-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-thiourea 

Relevant academic research and scientific papers

Synthesis of a tetrahydropyrano[2,3-d]oxazole analogue of trehazolin

Tetrahydropyrano[2,3-d]oxazole 6 as an analogue of trehazolin was synthesized from compound 3, which is a protected 1,3-bis(β-D-glucopyranosyl)thiourea. In contrast, compound 10, a protected 1,3-bis(α-D-glucopyranosyl)thiourea, and 15, a mixed species having one α-D-glucopyranosyl group and one β-D-glucopyranosyl group, did not yield the corresponding pyranooxazolines as anticipated, giving instead, respectively, a furo[2,3-d]oxazole 14 and a complex mixture of unidentified products.