F:Flammable;174973-66-1Relevant articles and documents
The Chemiluminescent Cycloreversion of an Anthracene-Benzene Biplanemer System both in the Solid State and in the Liquid State
Kimura, Masaru,Okamoto, Hideki,Kashino, Setsuo
, p. 2203 - 2212 (1994)
In the thermal cycloreversions of 9-anthracenecarboxylic acid-benzene 3a, methyl 9-anthracenecarboxylate-benzene 3b, dimethyl (or diethyl) 9,10-anthracenedicarboxylate-benzene 3c (or 3d) and anthracene-1,4-difluoro(or dichloro)benzene 3f (or 3g) biplanemers, chemiluminescence was observed for 3a-d only in the solid state at > 120 deg C but not in a liquid phase, while 3f and 3g were not chemiluminescent.Efficient chemiluminescence was observed in the photocycloreversion of all biplanemers tested in both phases.The thermodynamic parameters for the thermal cycloreversion of these biplanemers were collected.Higher activation energies were obtained in the solid state than in the liquid phase.The higher energies favor touch of the S0 surface with the S1 surface at the transition state for effecting the chemiluminescent cycloreversion.
Wavelength-Specific Product Desorption as a Key to Raising Nitrile Yield of Primary Alcohol Ammoxidation over Illuminated Pd Nanoparticles
Han, Pengfei,Tang, Cheng,Sarina, Sarina,Waclawik, Eric R.,Du, Aijun,Bottle, Steven E.,Fang, Yanfen,Huang, Yingping,Li, Kun,Zhu, Huai-Yong
, p. 2280 - 2289 (2022/02/14)
Research on visible-light photocatalysts of metal nanoparticles (NPs) has focused on increasing the reactant conversion by light-excited charges (electrons and positively charged holes). However, light irradiation can accelerate catalysis by other mechanisms. Here, we report that 650 nm wavelength irradiation of 0.75 W·cm-2 significantly increases nitrile yield of ammoxidation of primary aromatic alcohols with an ammonium salt over supported Pd NPs at 80 °C in air. We found that the desorption of the nitrile product from the catalyst is the rate-determining step; the irradiation promotes not only alcohol oxidation and subsequent aldehyde cyanation over the Pd NPs but also the nitrile desorption selectively via resonance energy transfer to achieve a high nitrile yield. This new mechanism provides a knob for the exquisite control of catalytic reaction pathways for ecofriendly synthesis.
Synthesis of Decorated Carbon Structures with Encapsulated Components by Low-Voltage Electric Discharge Treatment
Bodrikov, I. V.,Pryakhina, V. I.,Titov, D. Yu.,Titov, E. Yu.,Vorotyntsev, A. V.
, p. 60 - 69 (2022/03/17)
Abstract: Polycondensation of complexes of chloromethanes with triphenylphosphine by the action of low-voltage electric discharges in the liquid phase gives nanosized solid products. The elemental composition involving the generation of element distribution maps (scanning electron microscopy–energy dispersive X?ray spectroscopy mapping) and the component composition (by direct evolved gas analysis–mass spectrometry) of the solid products have been studied. The elemental and component compositions of the result-ing structures vary widely depending on the chlorine content in the substrate and on the amount of triphenylphosphine taken. Thermal desorption analysis revealed abnormal behavior of HCl and benzene present in the solid products. In thermal desorption spectra, these components appear at an uncharacteristically high temperature. The observed anomaly in the behavior of HCl is due to HCl binding into a complex of the solid anion HCI-2 with triphenyl(chloromethyl)phosphonium chloride, which requires a relatively high temperature (up to 800 K) to decompose. The abnormal behavior of benzene is associated with its encapsulated state in nanostructures. The appearance of benzene begins at 650 K and continues up to temperatures above 1300?K.
