175083-82-6Relevant academic research and scientific papers
Palladium-catalyzed reaction of 1-aza-5-germa-5-organobicyclo[3.3.3]undecane with aryl bromide
Kosugi, Masanori,Tanji, Tadatoshi,Tanaka, Yukio,Yoshida, Atsushi,Fugami, Keigo,Kameyama, Masayuki,Migita, Toshihiko
, p. 255 - 257 (2007/10/03)
Successive treatment of triallylamine with zirconocene chloride hydride and germanium tetrachloride affords 1-aza-5-germa-5-chlorobicyclo[3.3.3]undecane, which is converted to the 5-organo derivatives by the reaction with Grignard or lithium reagents. The organo groups showed higher reactivities toward Stille-type coupling than the corresponding organotributylgermanes.
