175167-80-3Relevant academic research and scientific papers
Synthesis of asymmetrical aryl-tin compounds by cleavage of alkyl-tin bonds with sodium metal in liquid ammonia followed by SRN1 reactions with chloroarenes
Yammal, Carlos C.,Podesta, Julio C.,Rossi, Roberto A.
, p. 1 - 8 (2007/10/03)
One methyl-tin bond was selectively cleaved from aryltrimethyltin compounds by sodium metal in liquid ammonia. The triorganylstannyl anions thus obtained are arylated by chloroarenes by means of photostimulated SRN1 reactions. Such reactions ca
