17522-85-9

Upstream product

• 16390-61-7 1-phenyl-1,2-closo-C₂B₁₀H₁₁ 
• 7704-34-9 sulfur 

Downstream Products

• 23273-97-4 triethylammonium salt of the 1-thio-2-phenyl-1,2-carborane anion 
• 856255-13-5 [1-SBr-2-Ph-1,2-closo-C₂B₁₀H₁₀] 
• 17525-40-5 [1-S-2-Ph-1,2-closo-C₂B₁₀H₁₀]2 
• 1202509-71-4 (o-C₂B₁₀H₁₀SPh)(PMe₂Ph)(pyridine)chloridopalladium(II) 
• 1350450-88-2 Pt[1-mercapto-2-phenyl-o-carborane]2[bis(diphenylphosphino)methane]*dichloromethane 
• 1350450-71-3 Pd[1-mercapto-2-phenyl-o-carborane]2[bis(diphenylphosphino)methane] 
• 1350450-87-1 Pt[1-mercapto-2-phenyl-o-carborane]2[PMe₂Ph]2 
• 146107-71-3 (C₁₀H₆(NMe₂)2H)(1-thiol-2-phenyl-1,2-dicarbadodecaborate⁽¹²⁾) 

Relevant academic research and scientific papers

Exo-π-bonding to an ortho-carborane hypercarbon atom: Systematic icosahedral cage distortions reflected in the structures of the fluoro-, hydroxy- and amino-carboranes, 1-X-2-Ph-1,2-C2B10H 10 (X = F, OH or NH2) and related anions

The structures of derivatives of phenyl-ortho-carborane bearing on the second cage hypercarbon atom a π-donor substituent (F, OH, O-, NH2, NH- and CH2-) were investigated by NMR, X-ray crystallography and computational studies. The molecular structures of these compounds, notably their cage C1-C2 distances and the orientations of their π-donor substituents (OH, NH2, NH - and CH2-) show remarkable and systematic variations with the degree of exo π-bonding, which varies as expected with the π-donor characteristics of the substituent.