17523-60-3

Upstream product

• 108-75-8 2,4,6-trimethyl-pyridine 
• 952-92-1 1-benzyl-1,4-dihydronicotinamide radical cation 
• 4460-71-3 BH₃ * 2,4,6-trimethylpyridine 
• 15454-31-6 iodate 

Downstream Products

• 108-75-8 2,4,6-trimethyl-pyridine 
• 571-60-8 1,4-Dihydroxynaphthalene 

Relevant academic research and scientific papers

Steric and kinetic isotope effects in the deprotonation of cation radicals of NADH synthetic analogues

The deprotonation rate constants and kinetic isotope effects of the cation radicals have been determined by combined use of direct electrochemical techniques at micro- and ultramicroelectrodes, redox catalysis, and laser flash photolysis, over a extended

Amine boranes. III. Propanolysis of pyridine boranes

The solvolysis kinetics in 1-propanol of a number of alkyl-substituted pyridine boranes was studied. The reactions were first order in amine borane. Linear variation of log k with pKa of the pyridinium ion was observed for groups of compounds with the same ortho substituents; steric enhancement of rate was attributed to 1.1 and 3.5 kcal./mole of strain relief in the transition state for one or two o-methyl groups, respectively. It was concluded that the solvolysis mechanism involves B-N cleavage in the slow step. It was found that the free energy of the transition state referred to the dissociation products was invariant with substitutions on the pyridine ring.