175234-45-4Relevant academic research and scientific papers
Preparation and reactivity of metal-containing monomers 44. Synthesis and structure of vinylporphyrins and their metal complexes
Kitsenko, N. A.,Ishkov, Yu. V.,Voloshanovskii, I. S.,Aliev, Z. G.,Pomogailo, A. D.
, p. 1758 - 1763 (1995)
Vinylporphyrins containing one vinyl group at the pyrrole or benzene ring and their complexes with Cu2+ and Zn2+ have been obtained by the Wittig reaction.Compounds obtained were characterized by physicochemical methods.X-ray diffraction analysis of 5-(4-vinylphenyl)-10.15,20-triphenylporphyrin has been carried out.It is likely that the inclusion of the vinyl group is accompanied by weak electron effects on the macrocycle.No nonequivalence of N-H bonds is observed in initial macrocycles. - Key words: vinylporphyrins, metal complexes; magnetic properties; crystal and molecular structure.
