175349-37-8

Basic information

• Product Name: 1-(1-Chloro-5-phenyl-pentylsulfanyl)-4-methyl-benzene
• CAS NO: 175349-37-8
• Molecular Weight: 304.884
• Mol File: 175349-37-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(1-Chloro-5-phenyl-pentylsulfanyl)-4-methyl-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1-Chloro-5-phenyl-pentylsulfanyl)-4-methyl-benzene(175349-37-8)
• EPA Substance Registry System: 1-(1-Chloro-5-phenyl-pentylsulfanyl)-4-methyl-benzene(175349-37-8)

Safety Data

• Hazardous Substances Data: 175349-37-8(Hazardous Substances Data)

Upstream product

• 10521-91-2 5-phenylpentan-1-ol 
• 103-19-5 di(p-tolyl) disulfide 
• 175349-36-7 (5-phenylpentyl)(p-tolyl)sulfane 

Downstream Products

• 420110-25-4 1-chloro-1-methyl-5-phenylpentyl p-tolyl sulfoxide 
• 103387-41-3 1,6-diphenyl-hex-1-ene 
• 828-14-8 (E)-hex-4-en-1-ylbenzene 
• 175349-38-9 1-chloro-5-phenylpentyl p-tolyl sulfoxide 

Relevant articles and documents

A method for generation of α-halo carbanions (carbenoids) from aryl α-haloalkyl sulfoxides with alkylmetals

Ligand exchange reaction of simple aryl α-haloalkyl sulfoxides with alkyllithium and ethylmagnesium halide at low temperature was investigated. On treatment of aryl α-haloalkyl sulfoxide with n-BuLi, t-BuLi, or EtMgX exclusively sulfur-alkyl bond-cleavage took place to afford α-halo carbanion (carbenoid). When this reaction was carried out without a proton source, the intermediate α-halo carbanion decomposed to give olefines in good yield. The ligand exchange reaction of sulfoxide was found to be very fast and the reaction could be carried out with a proton or a deuterium source (internal quench) to afford alkyl halide. This procedure offers a new method for preparing α-deuterated) halides (the halogen is F, Cl, or Br).