175349-95-8Relevant academic research and scientific papers
Synthesis of α, α-dideutero-β-amino esters
Chandrasekhar,Pendke, Mrunal,Muththe, Chandrashekar,Akondi, Srirama Murthy,Mainkar, Prathama S.
experimental part, p. 1292 - 1295 (2012/03/27)
A straight forward entry to α, α-dideutero-β-amino esters starting from the corresponding imines and deuterated acetonitrile has been developed involving a two-step process.
One-pot reductive n-alkylation with carbonyl compounds to give tertiary amines via borane reduction of imines
Tokizane, Masashi,Sato, Kaori,Sakami, Yuki,Imori, Yoichiro,Matsuo, Chika,Ohta, Tetsuo,Ito, Yoshihiko
scheme or table, p. 36 - 42 (2010/05/02)
One-pot synthesis of tertiary amines via borane-mediated reduction of imines and reductive N-alkylation with carbonyl compounds is described. This protocols reducing agent is only borane in the reduction of imines, and additional reductant is not necessary in reductive N-alkylation step. When using more than two equivalents of aldehydes, reductive N-alkylation proceeded in good yield.
Steric and electronic effects on the regioselective formation of platinum(II) metallacycles: Crystal structure of [PtMe(3-MeC6H3CH=NCH2C6H 5)(PPh3)]
Crespo, Margarita,Solans, Xavier,Font-Bardia, Merce
, p. 29 - 36 (2007/10/03)
The reaction of [Pt2Me4(μSMe2)2] (1) with imines 3,4-(OMe)2C6H3CH=NCH2Ph (2e) and 3-MeC6H4CH=NCH2Ph (2e) yields cyclometallated compou
