175448-32-5Relevant articles and documents
Iodine(V) reagents in organic synthesis. Part 2. Access to complex molecular architectures via Dess-Martin periodinane-generated o-imidoquinones
Nicolaou,Sugita,Baran,Zhong
, p. 2221 - 2232 (2007/10/03)
o-Imidoquinones, a rather rare class of compounds, are prepared from anilides by the action of Dess-Martin pedodinane (DMP) and water. Their chemistry has been extensively investigated and found to lead to p-quinones and polycyclic systems of diverse mole
Synthesis of anti-rheumatic agent epoxyquinomicin B
Matsumoto, Naoki,Iinuma, Hironobu,Sawa, Tsutomu,Takeuchi, Tomio
, p. 2945 - 2948 (2007/10/03)
Anti-rheumatic agent (±)-epoxyquinomicin B was synthesized for a 22% overall yield in eight steps from commercially available 3-hydroxy-4- nitrobenzaldehyde via the intermediate quinone 6 prepared by selective phenol oxidation of 5 by use of Fremy's salt as the key step.