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175478-20-3

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175478-20-3 Usage

General Description

(2R,6S)-2-Allyl-6-phenyl-1,2,3,6-tetrahydropyridine is a chemical compound with a tetrahydropyridine backbone that has an allyl and phenyl group attached. (2R,6S)-2-ALLYL-6-PHENYL-1,2,3,6-TETRAHYDROPYRIDINE is commonly used in the field of organic chemistry for various synthetic purposes as well as in pharmaceutical research and drug development. It can be used as a building block for the synthesis of various pharmaceutical compounds, and its structural features make it a versatile tool in the development of new drugs. Additionally, its unique structure and chemical properties make it a valuable target for study in the field of medicinal chemistry and toxicology.

Check Digit Verification of cas no

The CAS Registry Mumber 175478-20-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,5,4,7 and 8 respectively; the second part has 2 digits, 2 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 175478-20:
(8*1)+(7*7)+(6*5)+(5*4)+(4*7)+(3*8)+(2*2)+(1*0)=163
163 % 10 = 3
So 175478-20-3 is a valid CAS Registry Number.
InChI:InChI=1/C14H17N/c1-2-7-13-10-6-11-14(15-13)12-8-4-3-5-9-12/h2-6,8-9,11,13-15H,1,7,10H2/t13-,14+/m1/s1

175478-20-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name (2R,6S)-6-phenyl-2-prop-2-enyl-1,2,3,6-tetrahydropyridine

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:175478-20-3 SDS

175478-20-3Downstream Products

175478-20-3Relevant articles and documents

Preparation of trans- and cis-2-allyl-6-alkyl(aryl)-1,2,3,6-tetrahydropyridines based on the reductive trans-2,6-dialkylation of pyridine. Synthesis of (+/-)-epidihydropinidine and (+/-)-dihydropinidine

Bubnov, Yu. N.,Klimkina, E. V.,Ignatenko, A. V.

, p. 451 - 458 (2007/10/03)

A general method for the preparation of unsymmetrical trans-2-allyl-6-alkyl(aryl)-1,2,3,6-tetrahydropyridine 6 based on a combination of 1,2-addition of RLi to pyridine and trans-6-allylation with triallylborane in the presence of methanol was elaborated.It was shown that trans-piperidines 6 (R = Alk, Ph) isomerize into the corresponding cis-2-allyl-6-alkyl(phenyl)-3-piperidines 14 on heating with triallylborane followed by deboronation of aminoborane (16) with methanol and an alkali.The stereochemistry of compounds 6 and 14 was determined by two-dimensional NOE spectroscopy.A possible mechanism of the formation of trans-amines 6 and their transformation into cis-isomers discussed.Alkaloids (+/-)-epidihydropinidine (trans-2-methyl-6-propylpiperidine 2a, 70percent) and (+/-)-dihydropinidine (cis-2-methyl-6-propylpiperidine 1d, 71percent) were synthesized by hydrogenation of compound 6a (R = Me) and 14a (R = Me), respectively, over Raney nickel. - Keywords: allylboration; pyridine, 1,2-addition, alkyl(aryl)lithium, triallylborane; trans- and cis-2-allyl-6-alkyl(aryl)-1,2,3,6-tetrahydropyridines; trans-cis-isomerization; stereochemistry; piperidine alkaloids; (+/-)-epidihydropinidine; (+/-)-dihydropinidine.

Preparation of trans-2-allyl-6-alkyl(aryl)-1,2,3,6-tetrahydropyridines by reductive trans-2,6-dialkylation of pyridine. Synthesis of (±)-epidihydropinidine

Bubnov, Yuri N.,Klimkina, Elena V.,Ignatenko, Anatoly V.,Gridnev, Ilya D.

, p. 1317 - 1320 (2007/10/03)

A convenient method for the preparation of the title compounds involving the sequential treatment of pyridine with RLi (R = Alk, Ar), triallylborane and methanol is developed.

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