175602-66-1

Basic information

• Product Name: Cyclohexene, 3-ethoxy-1,5,5-trimethyl-
• CAS NO: 175602-66-1
• Molecular Formula: C11H20O
• Molecular Weight: 168.279
• Mol File: 175602-66-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 3-ethoxy-1,5,5-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 3-ethoxy-1,5,5-trimethyl-(175602-66-1)
• EPA Substance Registry System: Cyclohexene, 3-ethoxy-1,5,5-trimethyl-(175602-66-1)

Safety Data

• Hazardous Substances Data: 175602-66-1(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 470-99-5 isophorol 
• 19687-18-4 acetic acid 3,5,5-trimethylcyclohex-2-enyl ester 
• 78-59-1 3,5,5-Trimethylcyclohex-2-en-1-one 

Downstream Products

• 78-59-1 3,5,5-Trimethylcyclohex-2-en-1-one 

Relevant articles and documents

Reaction of cyclic allylic acetates with aliphatic alcohols in the presence of cerium(III) chloride

The reactions of selected allylic acetates with methanol, ethanol, n-propyl alcohol, isopropyl alcohol and tert-butyl alcohol in the presence of catalytic amounts of cerium(III) chloride are described. Allylic alkyl ethers, bis-allylic ethers and 1,3-dienes were obtained depending on the structure of the acetates.

Synthesis of Alkyl Allylic Ethers and 1,3-Dienes by the Reaction of Conjugated Cyclohexenones with Sodium Borohydride-Cerium(III) Chloride in Aliphatic Alcohols

The reaction of conjugated cyclohexenones 1,3-containing 3-methyl-2-en-1-one moiety with NaBH4/CeCl3*7H2O in primary aliphatic alcohols (MeOH, EtOH, n-PrOH) affords alkyl allylic ethers and 1,3-dienes.In isopropanol or tert-butanol only 1,3-dienes are obtained.Ketones 4-6 containing 2-methyl-2-en-1-one moiety are reduced under the same conditions to the corresponding allylic alcohols irrespective of the alcohol used.Key words: reduction, α,β-unsaturated ketones, allylic alcohols, alkyl allylic ethers, sodium borohydride, cerium(III) chloride