175671-32-6

Basic information

• Product Name: 1H-Indene-4-carboxaldehyde, 2,3,3a,4,5,7a-hexahydro-, (3aR,4R,7aR)- (9CI)
• Synonyms: 1H-Indene-4-carboxaldehyde, 2,3,3a,4,5,7a-hexahydro-, (3aR,4R,7aR)- (9CI)
• CAS NO: 175671-32-6
• Molecular Formula: C10H14O
• Molecular Weight: 150.21756
• Product Categories: ALDEHYDE
• Mol File: 175671-32-6.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1H-Indene-4-carboxaldehyde, 2,3,3a,4,5,7a-hexahydro-, (3aR,4R,7aR)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Indene-4-carboxaldehyde, 2,3,3a,4,5,7a-hexahydro-, (3aR,4R,7aR)- (9CI)(175671-32-6)
• EPA Substance Registry System: 1H-Indene-4-carboxaldehyde, 2,3,3a,4,5,7a-hexahydro-, (3aR,4R,7aR)- (9CI)(175671-32-6)

Safety Data

• Hazardous Substances Data: 175671-32-6(Hazardous Substances Data)

Usage

Molecular structure

A complex structure derived from indene, a bicyclic aromatic hydrocarbon.

Type of compound

An aldehyde, due to the presence of a carbonyl group.

Ring system

A six-membered ring fused to a five-membered ring.

Functional group

A carboxaldehyde group attached to the indene ring system.

Potential applications

Utilized in organic synthesis and chemical research due to its unique structure and potential reactivity.

Stereochemistry

(3aR,4R,7aR), indicating the compound's orientation in three-dimensional space, which is important for understanding its chemical behavior and applications.

Upstream product

• 159428-60-1 (2E,7E)-2,7,9-Decatrien-1-ol 
• 74930-35-1 hepta-4(E),6-dienecarbonitrile 
• 74930-36-2 (5E)-5,7-octadienal 
• 2409-89-4 methyl (2E,7E)-2,7,9-decatrien-1-oate 
• 1334145-28-6 C₁₀H₁₄O 

Relevant articles and documents

Asymmetric intramolecular Diels-Alder reactions of trienals catalyzed by chiral ruthenium Lewis acids

Chiral single-point binding ruthenium Lewis acid catalysts [Ru(acetone)((S,S)-BIPHOP-F)(Cp)][SbF6] ((S,S)-1a) and [Ru(acetone)((S,S)-BIPHOP-F)(indenyl)][SbF6] ((S,S)-1b) efficiently catalyze intramolecular Diels-Alder (IMDA) reactions of trienals under mild conditions to afford the endo cycloaddition products as the major products in good yields with high diastereo-and enantioselectivities. Schweizerische Chemische Gesellschaft.

Chiral ruthenium lewis acid catalyzed intramolecular diels - Alder reactions

Single point binding ruthenium Lewis acid catalysts [Ru(acetone)(S,S)- BIPHOP-F)Cp][SbF6] ((S,S)-1b) and [Ru(acetone)(S,S)-BIPHOP-F) (indenyl)][SbF6] ((S,S)-1c) efficiently catalyze intramolecular Diels - Alder (IMDA) reactions under mild conditions to afford the endo cycloaddition products as the major product in excellent yields with high diastereo- and enantioselectivities.