175671-56-4

Upstream product

• 1517-82-4 (-)-menthyl p-toluenesulfinate 
• 88362-46-3 (S)-4-isopropyl-2-methyl-Δ²-oxazoline 
• 103-19-5 di(p-tolyl) disulfide 
• 21681-88-9 (4-methylphenylthio)acetonitrile 
• 2026-48-4 (S)-valinol 
• 1517-82-4 (1R,2S,5R,SS)-(-)-menthyl p-toluenesulfinate 

Relevant academic research and scientific papers

Lewis acid-catalyzed asymmetric diels-alder reactions using chiral sulfoxide ligands: chiral 2-(arylsulfinylmethyl)-1,3-oxazoline derivatives.

New chiral sulfoxide-1,3-oxazoline ligands have been developed as chiral ligands for Lewis acid-catalyzed asymmetric Diels-Alder reactions. The use of chiral sulfinyl 1,3-oxazoline ligands in copper(II)-catalyzed asymmetric Diels-Alder reactions provided an endo cycloadduct as a major product with moderate enantioselectivity. A rationale is proposed for the mechanism of the asymmetric induction.

Diastereoselective conversion of sulfides into sulfoxides. 1,5- and 1,6-asymmetric induction

The diastereoselective oxidation of sulfides into sulfoxides has been achieved with enantiomerically pure dihydrooxazole auxiliaries. When an additional hydroxymethyl substituent is present, diastereocontrol is very high and 1,5-asymmetric induction has been achieved with up to 96:4 selectivity, and 1,6-asymmetric induction has been achieved with up to 97:3 selectivity in the absence of any additional chiral agents.