175719-99-0

Basic information

• Product Name: (+/-)-2,2'-bis(diphenylphosphino)-1,1'-(propane-1,3-diyl)ferrocene
• CAS NO: 175719-99-0
• Molecular Weight: 594.456
• Mol File: 175719-99-0.mol

Chemical Properties

• CAS DataBase Reference: (+/-)-2,2'-bis(diphenylphosphino)-1,1'-(propane-1,3-diyl)ferrocene(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-2,2'-bis(diphenylphosphino)-1,1'-(propane-1,3-diyl)ferrocene(175719-99-0)
• EPA Substance Registry System: (+/-)-2,2'-bis(diphenylphosphino)-1,1'-(propane-1,3-diyl)ferrocene(175719-99-0)

Safety Data

• Hazardous Substances Data: 175719-99-0(Hazardous Substances Data)

Upstream product

• 16853-85-3 lithium aluminium tetrahydride 

Relevant articles and documents

Isomeric diphosphines of a heteroannularly bridged ferrocene: Preparation, chromatographic separation and structure elucidation

Twofold lithiation of the heteroannularly bridged aminophosphine 5 yielded a mixture of five isomeric aminodiphosphines 7a-7d and 11, which were separated by adsorption chromatography. Their substitution pattern was elucidated by X-ray structure analyses and chemical correlation. Corresponding diphosphines 10a-10d were derived with moderate yields via acetates 8a-8d. A search for stable conformers of 7a-7d and 11 was conducted using empirical force field calculations. Calculated minimum-energy geometries were compared with crystal structures of 7a, 7c and 7d.