17576-37-3Relevant academic research and scientific papers
Aminolysis of aryl N-ethyl thionocarbamates: Cooperative effects of atom pairs O and S on the reactivity and mechanism
Oh, Hyuck Keun,Oh, Ji Young,Sung, Dae Dong,Lee, Ikchoon
, p. 5624 - 5629 (2007/10/03)
The aminolysis reactions of aryl N-ethyl thionocarbamates (ETNC/EtHN-C(=S)-OC6H4Z) with benzylamines (XC 6H4CH2NH2) in acetonitrile are investigated at 30.0 °C. The rate of ETNC is slower b
Process for producing an aliphatic isocyanate
-
, (2008/06/13)
A process for producing an aliphatic isocyanate from an aliphatic primary amine comprising a carbonylation step in which an aliphatic primary amine is allowed to react with carbon monoxide at a temperature of about 100°-250° C. in the presence of an aromatic hydroxyl compound having a pKa value of not more than about 11, molecular oxygen and a catalyst system comprising at least one member selected from palladium and rhodium metals and components thereof and at least one member selected from iodine and bromine and compounds thereof and a combined separation and recovery step comprising a pyrolysis-distillation reaction in which the mixture of carbonylated products is heated to a temperature of from about 100° to 300° C.
