17586-63-9Relevant academic research and scientific papers
Carbon-iodide bond activation by cyclometalated Pt (II) complexes bearing tricyclohexylphosphine ligand: A comparative kinetic study and theoretical elucidation
Chamyani, Samira,Shahsavari, Hamid R.,Abedanzadeh, Sedigheh,Golbon Haghighi, Mohsen,Shabani, Sepideh,Notash, Behrouz
, (2019)
Cyclometalated Pt (II) complexes [PtMe(C^N)(L)], in which C^N?=?deprotonated 2,2′-bipyridine N-oxide (Obpy), 1, deprotonated 2-phenylpyridine (ppy), 2, deprotonated benzo [h] quinolone (bzq), 3, and L?=?tricyclohexylphosphine (PCy3) were prepar
Synthesis, Isolation and Crystal Structures of the Metalated Ylides [Cy3P-C-SO2Tol]M (M = Li, Na, K)
Darmandeh, Heidar,Scherpf, Thorsten,Feichtner, Kai-Stephan,Schwarz, Christopher,Gessner, Viktoria H.
, p. 835 - 841 (2020/05/06)
The preparation and isolation of the metalated ylides [Cy3PCSO2Tol]M (Cy1-M) (with M = Li, Na, K) are reported. In contrast to its triphenylphosphonium analogue the synthesis of Cy1-M revealed to be less straigh
Highly Efficient and Convenient Access to Phosphinates via CHCl3-Assisted Direct Phosphorylation between R2P(O)H and ROH by Phosphonium Salt Catalysis
Jiang, Zhiyu,Wang, Tianli,Yu, Xiaojun,Zhang, Hong-Su,Zhang, Song
supporting information, (2020/05/25)
A mild, efficient, convenient and scalable method to synthesize phosphinates via direct phosphorylation between R2P(O)H and ROH was developed. All aromatic substrates completed this transformation with excellent yields (up to 98 %), and preliminary mechanistic studies suggest that a carbene-involving process from CHCl3 to CH2Cl2 facilitates the phosphorylation.
Thermal decomposition modes for four-coordinate ruthenium phosphonium alkylidene olefin metathesis catalysts
Leitao, Erin M.,Dubberley, Stuart R.,Piers, Warren E.,Wu, Qiao,McDonald, Robert
supporting information; experimental part, p. 11565 - 11572 (2009/12/07)
The four-coordinate ruthenium phosphonium alkylidenes 1-Cy and 1-iPr, differing in the substituent on the phosphorus center, were observed to decompose thermally in the presence of 1,1-dichloroethylene to produce [H 3CPR3][Cl]. The m
