176088-47-4

Basic information

• Product Name: Naphthalene, 6-bromo-1,2,3,4-tetrahydro-1,1-dimethyl-
• CAS NO: 176088-47-4
• Molecular Formula: C12H15Br
• Molecular Weight: 239.155
• Mol File: 176088-47-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Naphthalene, 6-bromo-1,2,3,4-tetrahydro-1,1-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Naphthalene, 6-bromo-1,2,3,4-tetrahydro-1,1-dimethyl-(176088-47-4)
• EPA Substance Registry System: Naphthalene, 6-bromo-1,2,3,4-tetrahydro-1,1-dimethyl-(176088-47-4)

Safety Data

• Hazardous Substances Data: 176088-47-4(Hazardous Substances Data)

Upstream product

• 691-37-2 4-Methyl-1-pentene 
• 1426083-16-0 bis(3-bromophenyl)iodonium triflate 
• 3123-97-5 dihydro-5,5-dimethyl-2(3H)-furanone 

Downstream Products

• 166978-34-3 methyl (E)-4-(2-(5,5-dimethyl-8-oxo-5,6,7,8-tetrahydronaphthalen-2-yl)vinyl)benzoate 
• 166978-46-7 7-bromo-4,4-dimethyl-3,4-dihydro-2H-naphthalen-1-one 
• 205385-92-8 (S)-2-{[3-(2-tert-Butoxycarbonylamino-3-hydroxy-propyl)-8,8-dimethyl-5,6,7,8-tetrahydro-naphthalen-2-yl]-methyl-amino}-3-methyl-butyric acid benzyl ester 

Relevant articles and documents

Cu-Catalyzed cascades to carbocycles: Union of diaryliodonium salts with alkenes or alkynes exploiting remote carbocations

Copper-catalyzed cascade reactions between alkenes or alkynes and diaryliodonium salts form carbocyclic products in a single step. Arylation of the unsaturated functional group is proposed to form a carbocation intermediate that facilitates hydride shift pathways to translocate the positive charge to a remote position and enables ring formation via a Friedel-Crafts-type reaction.