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Ir(triflato)(tetrafluorobenzobarrelene)(PCy3) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 176247-65-7 Structure
  • Basic information

    1. Product Name: Ir(triflato)(tetrafluorobenzobarrelene)(PCy3)
    2. Synonyms:
    3. CAS NO:176247-65-7
    4. Molecular Formula:
    5. Molecular Weight: 847.897
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 176247-65-7.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Ir(triflato)(tetrafluorobenzobarrelene)(PCy3)(CAS DataBase Reference)
    10. NIST Chemistry Reference: Ir(triflato)(tetrafluorobenzobarrelene)(PCy3)(176247-65-7)
    11. EPA Substance Registry System: Ir(triflato)(tetrafluorobenzobarrelene)(PCy3)(176247-65-7)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 176247-65-7(Hazardous Substances Data)

176247-65-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 176247-65-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,6,2,4 and 7 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 176247-65:
(8*1)+(7*7)+(6*6)+(5*2)+(4*4)+(3*7)+(2*6)+(1*5)=157
157 % 10 = 7
So 176247-65-7 is a valid CAS Registry Number.

176247-65-7Downstream Products

176247-65-7Relevant articles and documents

Reactions of IrXL2(PR3) (X = Cl, OTf; L2 = TFB, 2CO) with HSnR3 (R = Ph, nBu)

Chen, Wanzhi,Esteruelas, Miguel A.,Martin, Marta,Olivan, Montserrat,Oro, Luis A.

, p. 95 - 103 (1997)

The reactions of several square-planar IrXL2(PR3) complexes with HSnR3 have been studied. The oxidative addition of HSnPh3 to the complexes IrCl(TFB)(PR3) (TFB = tetrafluorobenzobarrelene, PR3/s

Synthesis and characterization of IrH2{Si(OTf)Ph2}(TFB)(PR3) (PR3 = PiPr3, PCy3): First base-stabilized silylene complexes of iridium

Chen, Wanzhi,Edwards, Andrew J.,Esteruelas, Miguel A.,Lahoz, Fernando J.,Oliván, Montserrat,Oro, Luis A.

, p. 2185 - 2188 (2008/10/08)

The reactions of H2SiPh2 with the triflato complexes Ir(OTf)(TFB)(PR3) afford the base-stabilized silylene complexes IrH2{Si(OTf)Ph2}(TFB)(PR3) (TFB = tetrafluorobenzobarrelene; PR3 = PiPr3, PCy3). The single-crystal X-ray structural analysis of IrH2{Si(OTf)-Ph2}(TFB)(PiPr3) has been performed. The distances Ir-Si (2.337(2) ?) and Si-O (1.790(5) ?) as well as the summation of angles at silicon, ignoring the Si-OTf bond (343.5°), are in agreement with the partial unsaturated character of the base-stabilized silylene ligand.

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