176445-50-4Relevant academic research and scientific papers
Study of the complexing properties toward RuII of new polydentate amphiphilic phosphines containing polyether chains. Unprecedented η3 mode of bonding of the new ligand PPh[(CH2)3CHMe2][(CH2CH 2O)3Me] and study of its hemilabile character
Valls, Esteve,Suades, Joan,Donadieu, Bruno,Mathieu, Rene
, p. 771 - 772 (2007/10/03)
New polydentate amphiphilic phosphines containing polyether chains are prepared; unprecedented coordination and reactivity of the hemilabile ligand PPh[(CH2)3CHMe2][(CH2CH 2O)3Me] are found; the η3 mode of bonding of this ligand is demonstrated by X-ray crystallographic studies.
