176509-13-0

Basic information

• Product Name: Pd[(η5-C5H3)CCH3NCH2C6H5][Fe(η5-C5H5]ClP(C2H5)3
• CAS NO: 176509-13-0
• Molecular Weight: 576.237
• Mol File: 176509-13-0.mol

Chemical Properties

• CAS DataBase Reference: Pd[(η5-C5H3)CCH3NCH2C6H5][Fe(η5-C5H5]ClP(C2H5)3(CAS DataBase Reference)
• NIST Chemistry Reference: Pd[(η5-C5H3)CCH3NCH2C6H5][Fe(η5-C5H5]ClP(C2H5)3(176509-13-0)
• EPA Substance Registry System: Pd[(η5-C5H3)CCH3NCH2C6H5][Fe(η5-C5H5]ClP(C2H5)3(176509-13-0)

Safety Data

• Hazardous Substances Data: 176509-13-0(Hazardous Substances Data)

Upstream product

• 156279-09-3 [Pd[(η5-C5H3)CCH3NCH2C6H5][Fe(η5-C5H5)(μ-Cl)]]2 
• 554-70-1 triethylphosphine 

Relevant articles and documents

Factors affecting the lability of the Pd-N bonds in palladacycles containing a σ(Pd-Csp2, ferrocene) bond. X-ray crystal structures of [Pd{[(η5-C5H3)-C(Me)=N-R]Fe (η5-C5H5)}C1(L)]

The syntheses, characterization and molecular structures of the cyclopalladated complexes [Pd{[(η5-C5H3)-C(Me)=N-CH 2-C6H5]Fe(η5- C5H5)}Cl(PEt3)] (1) and [Pd{[(η5-C5H3)-C (Me)=N-C6H4-4-Me]Fe(η5-C 5H5)}Cl(PPh2Et)] (2) are reported. A comparative study of the reactivity of 1 and 2 in front of PEt3, reveals that the Pd-N bond is more prone to cleavage in 2 than in 1. These results have been interpreted on the basis of the differences detected in the structural characteristics of this sort of derivatives.