17663-27-3Relevant articles and documents
HYDRODIMERIZATION OF UNSATURATED ALCOHOLS, ESTERS, NITRILES, KETONES, AMINES, SILANES, EPOXIDES AND FLUOROCARBONS BY MERCURY-PHOTOSENSITIZATION
Muedas, Cesar A.,Ferguson, Richard R.,Crabtree, Robert H.
, p. 3389 - 3392 (1989)
Substituted alkenes are efficiently hydrodimerized on a preparative scale in an H2 atmosphere by Hg(vapor) and 254 nm light.
REDUCTIVE COUPLING OF α,β-ENONES PROMOTED BY Mg AND Mg-MgBr2
Pons, Jean-Marc,Santelli, Maurice
, p. 3679 - 3682 (2007/10/02)
α,β-enones able to have a s-cis conformation can be reduced by Mg (turnings 99.8percent) or more efficiently by Mg(99.8percent)-MgBr2, 10 Et2O in dimers (resulting from the formation of a bond between the Cβ carbon atoms) and dihydroketones.