176643-86-0Relevant academic research and scientific papers
The Role of Silicon-Oxygen Interactions in Determining the Stereochemical Outcome of the Peterson Reaction
Bassindale, Alan R.,Ellis, Richard J.,Taylor, Peter G.
, p. 34 - 35 (2007/10/03)
The electronic effect of substituents on a benzene ring on the stereochemical outcome of the reaction of an α-triarylsilyl carbanion with an aldehyde is examined: the results can be interpreted in terms of the mode of approach of the carbanion towards the prochiral aldehyde, taking into account a variable oxygen-silicon interaction.
