176690-29-2

Upstream product

• 1396797-88-8 2-(3-fluoropropyl)-1-methylindole 
• 4294-57-9 para-methylphenylmagnesium bromide 

Downstream Products

• 133198-11-5 (E)-3-<(N-hydroxy-N-phenyl)-amino>-2--indole 
• 1211485-58-3 (2S,3R,4R)-2,9-dimethyl-3-nitro-4-phenyl-2,3,4,9-tetrahydro-1H-carbazole 
• 1211485-67-4 (2S,3R,4R)-4-(3,4-difluorophenyl)-2,9-dimethyl-3-nitro-2,3,4,9-tetrahydro-1H-carbazole 
• 1211485-68-5 (2S,3R,4R)-2,9-dimethyl-3-nitro-4-p-tolyl-2,3,4,9-tetrahydro-1H-carbazole 
• 1211485-59-4 (2S,3R,4R)-4-(4-fluorophenyl)-2,9-dimethyl-3-nitro-2,3,4,9-tetrahydro-1H-carbazole 
• 1211485-64-1 (2S,3R,4R)-4-(-bromophenyl)-2,9-dimethyl-3-nitro-2,3,4,9-tetrahydro-1H-carbazole 
• 1211485-60-7 (2S,3R,4R)-4-(4-chlorophenyl)-2,9-dimethyl-3-nitro-2,3,4,9-tetrahydro-1H-carbazole 
• 1211485-66-3 (2S,3R,4S)-4-(2-chlorophenyl)-2,9-dimethyl-3-nitro-2,3,4,9-tetrahydro-1H-carbazole 

Relevant academic research and scientific papers

Dinuclear iron complex-catalyzed cross-coupling of primary alkyl fluorides with aryl grignard reagents

Iron-catalyzed cross-coupling of nonactivated primary alkyl fluorides with aryl Grignard reagents has been achieved by using the low-coordinate dinuclear iron complex [(IPr2Me2)Fe(μ2-NDipp) 2Fe(IPr2Me2)] as the catalyst. This iron-catalyzed C(sp3)-F bond arylation reaction is applicable to a variety of aryl Grignard reagents and primary alkyl fluorides. The product pattern suggests the involvement of a radical-type mechanism for its C-F bond scission step.