Cas 176698-33-2,[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-O)]

176698-33-2

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Product Name: [Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-O)]
Synonyms:
CAS NO:176698-33-2
Molecular Formula:
Molecular Weight: 970.857
EINECS: N/A
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Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
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Density: N/A
Refractive Index: N/A
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Solubility: N/A
CAS DataBase Reference: [Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-O)](CAS DataBase Reference)
NIST Chemistry Reference: [Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-O)](176698-33-2)
EPA Substance Registry System: [Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-O)](176698-33-2)

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Hazardous Substances Data: 176698-33-2(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 176698-33-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,6,6,9 and 8 respectively; the second part has 2 digits, 3 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 176698-33:
(8*1)+(7*7)+(6*6)+(5*6)+(4*9)+(3*8)+(2*3)+(1*3)=192
192 % 10 = 2
So 176698-33-2 is a valid CAS Registry Number.

176698-33-2Upstream product

177019-12-4 [Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-SO2)]

176698-33-2Downstream Products

176698-33-2Relevant academic research and scientific papers

Oxidation at a Dimolybdenum(V) Sulfur Bridge. Formation of so and SO2 Bridges. Facile Extrusion of so from the SO2 Bridge

Wang, Runtong,Mashuta, Mark S.,Richardson, John F.,Noble, Mark E.

, p. 3022 - 3030 (2008/10/09)

Peroxide oxygenation of μ-thiolate-μ-sulfide Mo(V) dimer complexes of the type [Mo2(NAr)2(S2P(OEt)2) 2(μO2CMe)(μ-SR)(μ-S)] yielded Mo2(μ-SO) and Mo2(μ-SO2) complexes, demonstrating the reactivity sequence μ-S > μ-SO ? μ-SR. Inversion isomers of the pyramidal sulfur site in the μ-SO bridge were observed, and the pyramidicity was confirmed crystallographically. Visible light photolysis of the Mo2(μ-SO2) complex liberated SO from the SO2 bridge and produced Mo2(μ-O) compounds. Crystallography of analogous Mo2(μ-S), Mo2(μ-SO), Mo2(μ-SO2), and Mo2(μ-O) complexes provided structural comparisons related to variations in the bridge functionality. For 2, Mo2C31H44N2O6P 2S6: a = 13.604(5) A?, b = 15.280(4) A?, c = 12.502(2) A?, α = 93.36(2)°, β = 112.00 (2)°, γ = 76.01(2)°, triclinic, P1, Z = 2. For 3, Mo2C31H44N2O7P 2S6: a = 12.535(2) A?, b = 25.299-(9) A?, c = 13.989(5) A?, β = 99.99(2)°, monoclinic, P21/n, Z = 4. For 4, Mo2C31H44N2O8P 2S6: a = 12.591(9) A?, b = 25.34(1) A?, c = 14.048(3) A?, β = 100.79(4)°, monoclinic, P21/n, Z = 4. For 5, Mo2C31H44N2O7P 2S5: a = 13.731(5) A?, b = 19.267(4) A?, c = 16.652(5) A?, β = 104.78(3)°, monoclinic, P21/n, Z = 4.

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