176713-80-7Relevant academic research and scientific papers
Palladium-Catalyzed Hydroarylation of Diazocarboxylates and Diazophosphonates
Beletskaya, Irina P.,Golitsin, Sergey M.,Titanyuk, Igor D.
, p. 775 - 780 (2020)
A simple synthetic procedure for the Pd-catalyzed hydro-arylation of diazoacetic ester has been previously developed in our laboratory. Now we have applied this methodology for hydroarylation of α-diazocarboxylates/α-diazophosphonates. Diazo compounds reacted with aryl iodides and formic acid to afford diarylated esters or phosphonates in yields up to 71percent.
Synthesis of α-(nitroaryl)benzylphosphonates via oxidative nucleophilic substitution of hydrogen in nitroarenes
Makosza, Mieczyslaw,Sulikowski, Daniel
scheme or table, p. 3827 - 3832 (2009/10/01)
(Chemical Equation Presented) Carbanions of diethyl benzylphosphonate and diethyl 1-phenylethylphosphonate add to nitroarenes to form relatively long-lived σH adducts that can be oxidized to products of oxidative nucleophilic substitution of hy
