176962-46-2Relevant academic research and scientific papers
Sequential multiple-photon photochemistry of sterically congested enones
Schnapp, Karlyn A.,Motz, Philip L.,Stoeckel, Sharon M.,Wilson, R. Marshall,Krause Bauer, Jeanette A.,Bohne, Cornelia
, p. 2317 - 2320 (2007/10/03)
The photochemistry of sterically hindered enones 1 and 2 is described. A novel photorearrangement occurs in both systems which involves carbonyl attack on the adjacent phenyl ring, expansion of that ring to a cycloheptatriene and subsequent photochemically induced 1,7-phenyl migration.
