17698-51-0

Upstream product

• 108-98-5 thiophenol 
• 99-73-0 para-bromophenacyl bromide 
• 2039-82-9 1-bromo-4-ethenyl-benzene 
• 1193-82-4 racemic methyl phenyl sulfoxide 
• 201230-82-2 carbon monoxide 
• 31268-20-9 bromomethyl phenyl sulfoxide 
• 5467-74-3 4-Bromophenylboronic acid 

Relevant academic research and scientific papers

Visible light organophotoredox catalysis: A general approach to β-keto sulfoxidation of alkenes

A mild, simple, efficient and metal-free approach to β-keto sulfoxides utilising eosin Y as an organophotoredox catalyst has been developed. This general protocol offers a direct and rapid difunctionalization of alkenes using thiophenols and atmospheric oxygen at room temperature in a one-pot procedure. The utilisation of visible light and air (O2) as inexpensive, readily available, non-toxic and eco-sustainable reagents makes this protocol compatible with the green chemistry demands. This journal is the Partner Organisations 2014.

First synthesis of β-keto sulfoxides by a palladium-catalyzed carbonylative suzuki reaction

(Chemical Equation Presented) An unprecedented palladium-catalyzed three-component cross-coupling reaction between α-bromo sulfoxide, carbon monoxide, and aromatic boronic acids provides a new and efficient approach to the synthesis of β-ketosulfoxides. T