177159-58-9

Upstream product

• 120-07-0 2,2'-(phenylimino)bis[ethanol] 
• 76874-79-8 2-amino-4-chloro-5-formyl-1,3-thiazole 

Downstream Products

• 1254561-06-2 C₂₉H₂₃ClN₆O₆S₂ 
• 1254561-04-0 C₃₀H₂₃ClN₆O₅S 
• 177159-70-5 C₂₅H₁₉ClN₆O₄S₂ 
• 1307309-09-6 C₂₆H₁₉ClN₆O₃S 
• 716378-72-2 C₂₅H₂₂ClN₇O₃S 
• 935853-60-4 C₂₃H₂₀ClN₅O₄S 

Relevant academic research and scientific papers

High nonlinear optical response in 4-chlorothiazole-based azo dyes

Four azo dyes showing high nonlinear optical properties were prepared, based on a 4-chlorothiazole azo moiety functionalized with strong acceptor groups and/or further donor/acceptor groups along the conjugated backbone. The effects of the acceptors as we

Modulated conjugation as a means of improving the intrinsic hyperpolarizability

A new strategy for optimizing the first hyperpolarizability based on theconcept of a modulated conjugated path in linear molecules is investiga ted. A series of seven novel chromophores with different types of conjugated paths were synthesized and characterized. Hyper-Rayleigh scatteringexperiments confirmed that modulated conjugation paths that include ben zene, thiophene, and/or thiazole rings in combination with azo and/or ethenyl linkages between dihydroxyethylamino donor groups and various acceptor groups result in enhanced intrinsic hyperpolarizabilities that exceed the long-standing apparent limit for two of the chromophores. The experimental results are analyzed and interpreted in the context of quantumlimits, which show that conjugation modulation of the bridge in donor/a cceptor molecules simultaneously optimizes the transition moments and the energy-level spacing.

Second-order optical nonlinearity of in situ prepared polyurethanes having thiazolylazo chromophores

The in situ prepared polyurethane films of the thiazolylazo NLOphores showed d33 values of 38-49 pm V-1. The temporal stability of the poled NLOphore was in the following order of the polymers: network > side chain > main chain.