177271-99-7Relevant academic research and scientific papers
Dinuclear addition of the Pd-Pd moieties to 1,3-dienes
Murahashi, Tetsuro,Nagai, Tomoki,Nakashima, Hiromitsu,Tomiyasu, Sadayuki,Kurosawa, Hideo
, p. 754 - 755 (2006)
The reaction of a substitutionally labile dipalladium(I) complex [Pd 2(CH3CN)6][BF4]2 with isoprene or 1,3-butadiene in acetonitrile afforded [Pd2(μ- η3:η1-C5H8)(CH 3CN)5][BF4]2 or [Pd 2(μ-η3:η1-C4H 6)(CH3CN)5][BF4]2. The structure of the isoprene complex was determined by X-ray crystallographic analyses. The interconversion between the [Pd2(μ- η3:η1-C5H8)-(CH 3CN)5][BF4]2 and [Pd 2(μ-η2:η2-C5H 8)-(μ-Cl)Cl2][PPh4] occurred facilely. Copyright
