177282-83-6

Basic information

• Product Name: Me₃In(1,2-bis(diphenylphosphino)ethane)InMe₂Et * Me₃In(1,2-bis(diphenylphosphino)ethane)InMe₃
• CAS NO: 177282-83-6
• Molecular Weight: 1450.57
• Mol File: 177282-83-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Me₃In(1,2-bis(diphenylphosphino)ethane)InMe₂Et * Me₃In(1,2-bis(diphenylphosphino)ethane)InMe₃(CAS DataBase Reference)
• NIST Chemistry Reference: Me₃In(1,2-bis(diphenylphosphino)ethane)InMe₂Et * Me₃In(1,2-bis(diphenylphosphino)ethane)InMe₃(177282-83-6)
• EPA Substance Registry System: Me₃In(1,2-bis(diphenylphosphino)ethane)InMe₂Et * Me₃In(1,2-bis(diphenylphosphino)ethane)InMe₃(177282-83-6)

Safety Data

• Hazardous Substances Data: 177282-83-6(Hazardous Substances Data)

Upstream product

• 102091-56-5 dimethylethylindium(III) 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 

Relevant articles and documents

Synthesis, mass spectrometry and nmr spectroscopy studies of the (ch3) 2in(c2h5) system: X-ray crystal structure of a diphosphine-bridged complex

The synthesis of homoleptic and heteroleptic alkylindium derivatives (generally as diethyl ether adducts) was carried out in high yields from InI3. The nuclear magnetic resonance and mass spectra of the compounds MenInEt3n (n = 0, 1, 2, or 3) and of their trideuteromethyl analogues showed that both heteroleptic Me2InEt and MeInEt2 exist as single compounds, although disproportionation to InMe3 and InEt3 has been observed at temperatures slightly higher than room temperature. The crystal structure of unusual diphosphine-bridged adduct, [(InMe3)diphos(Me2InEt)] · [(InMe3)diphos(InMe3)], (diphos = (C6H5)2PCH2CH2P(C6H5)2 is reported.