177481-85-5Relevant academic research and scientific papers
A versatile and highly stereoselective access to vinyl triflates derived from 1,3-dicarbonyl and related compounds
Specklin, Simon,Bertus, Philippe,Weibel, Jean-Marc,Pale, Patrick
supporting information; experimental part, p. 7845 - 7848 (2009/04/11)
(Chemical Equation Presented) 1,3-Dicarbonyl derivatives, such as 1,3-diketones, β-ketoaldehydes, β-ketoesters, β-ketoamides, β-ketophosphonates and β-ketosulfones were efficiently converted to the corresponding Z vinyl triflates with high stereoselectivi
Synthesis of 6-/10-membered ring analogs of the dienediyne core of the neocarzinostatin chromophore by palladium(0)-mediated ring-closure reactions
Brickmann, Kay,Hambloch, Frank,Suffert, Jean,Brueckner, Reinhard
, p. 457 - 471 (2007/10/03)
A strategy for the synthesis of the benzo-annulated bicyclic dienediyne analogs 46 and 48 of the DNA-cleaving natural product neocarzinostatin chromophore was developed. 2-Formylcyclohexanone (9) was converted stereoselectively first into the mono(enol tr
