177489-93-9

Basic information

• Product Name: 3-benzyloxycyclohept-2-en-1-one
• CAS NO: 177489-93-9
• Molecular Weight: 216.28
• Mol File: 177489-93-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-benzyloxycyclohept-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-benzyloxycyclohept-2-en-1-one(177489-93-9)
• EPA Substance Registry System: 3-benzyloxycyclohept-2-en-1-one(177489-93-9)

Safety Data

• Hazardous Substances Data: 177489-93-9(Hazardous Substances Data)

Upstream product

• 1194-18-9 cycloheptane-1,3-dione 
• 81927-55-1 O-benzyl 2,2,2-trichloroacetimidate 
• 6838-67-1 1,2-bis(trimethylsilyloxy)cyclohex-1-ene 
• 59454-28-3 1,6-Bis-(trimethylsiloxy)-bicyclo[4,1,0]heptan 
• 141-28-6 diethyl adipate 

Relevant articles and documents

Cascade reactions of methyl-2-chloro-2-cyclopropylideneacetate with five- and seven-membered cyclic dienolates: A novel approach to the bicyclo[4.2.1]nonane segment of the skeleton of mediterraneols

The MIMIRC (Michael-Michael-Ring Closure) reaction of methyl 2-chloro-2-cyclopropylideneacetate (5) with the cyclic dienolates 6a, 6c, and the one derived from 11-R under aprotic conditions gave the tricyclic adducts 7a, 7c, and 10-R, respectively, in moderate to good yield. Compound 10-R is conceived as a potential intermediate for the synthesis of the biologically active marine diterpenes mediterraneol 1.