17755-52-1

Usage

Uses

Used in Coordination Chemistry:
1-(2-Pyridyl)-2-(3-pyridyl)-ethylene is used as a ligand in coordination chemistry for forming complexes with transition metal ions. Its ability to coordinate in different geometries contributes to the diversity of coordination complexes that can be synthesized.
Used in Metallopolymer Preparation:
In the field of materials science, 1-(2-Pyridyl)-2-(3-pyridyl)-ethylene is used as a component in the preparation of metallopolymers. Its coordination properties with metal ions facilitate the development of new materials with potential applications in various industries.
Used in Catalysis:
1-(2-Pyridyl)-2-(3-pyridyl)-ethylene is utilized in catalysis as a ligand to create catalytically active complexes. Its coordination with metal ions can enhance the catalytic performance in various chemical reactions.
Used in Medicinal Chemistry:
In medicinal chemistry, 1-(2-Pyridyl)-2-(3-pyridyl)-ethylene is used for the synthesis of metal-based pharmaceuticals. Its coordination chemistry allows for the development of metal complexes with potential therapeutic properties.
Overall, 1-(2-Pyridyl)-2-(3-pyridyl)-ethylene is a multifaceted compound with applications spanning across coordination chemistry, materials science, catalysis, and medicinal chemistry due to its unique ability to form complexes with metal ions.

InChI:InChI=1/C12H10N2/c1-2-9-14-12(5-1)7-6-11-4-3-8-13-10-11/h1-10H

Upstream product

• 55384-98-0 2,3'-(ethyne-1,2-diyl)dipyridine 
• 105789-71-7 1,2-dibromo-1-[2]pyridyl-2-[3]pyridyl-ethane 
• 13362-75-9 trans-1-(2-pyridyl)-2-(3-pyridyl)ethylene 
• 10299-54-4 2-[2]pyridyl-1-[3]pyridyl-ethanol 
• 614-18-6 3-pyridinecarboxylic acid ethyl ester 
• 100-69-6 2-vinylpyridine 
• 626-55-1 3-Bromopyridine 
• 109-06-8 α-picoline 
• 500-22-1 3-pyridinecarboxaldehyde 
• 59576-33-9 2-(2-pyridinyl)-1-(3-pyridinyl)ethanone 

Downstream Products

• 14802-38-1 cis-1-[2]Pyridyl-2-[3]pyridyl-aethen 

Relevant academic research and scientific papers

[2+2] Photodimerization of Stilbazoles Promoted by Oxalic Acid in Suspension

In this study, a very simple technique to perform efficiently photodimerization of some vinylpyridines is reported. By irradiating a stirred mixture of several stilbazoles with solid oxalic acid dihydrate dispersed in a nonpolar (i.e., cyclohexane) or moderately polar (benzene, dichloromethane, dioxane) solvent, the corresponding dimeric cyclobutane adducts were obtained in high yields and excellent regio- and stereoselectivities. The strategy could also be applied successfully to oily, waxy, or even insoluble stilbazoles. Moreover, the oxalic acid loading could be lowered to substoichiometric amounts. When further optimizations were needed, our strategy was found to be highly flexible to identify other oligocarboxylic acids as alternative additives to improve, or even overturn, the regioselectivity. Oxalic acid and other oligocarboxylic acids were found to be capable of orienting more than 50 stilbazoles toward photodimerization under these conditions.

Palladium- meta -terarylphosphine catalyst for the Mizoroki-Heck reaction of (hetero)aryl bromides and functional olefins

The evolutionary meta-terarylphosphine ligand architecture of Cy?Phine was recently shown to be a key feature that imposed outstanding performance in palladium-catalyzed copper-free Sonogashira applications. Herein, the Pd-Cy?Phine combination has similar

Can Palladium Acetate Lose Its "saltiness"? Catalytic Activities of the Impurities in Palladium Acetate

Commercially available palladium acetate often contains two major impurities, whose presence can impact the overall catalytic efficacy. This systematic study provides a comparison of the differences in catalytic activity of pure palladium acetate, Pd3(OAc)6, with the two impurities: Pd3(OAc)5(NO2) and polymeric [Pd(OAc)2]n in a variety of cross-coupling reactions. The solid state 13C NMR spectra of all three compounds in conjunction with DFT calculations confirm their reported geometries.

Heck cross-coupling of vinyl heteroaromatic compounds with aryl and heteroaryl halides using Pd(II) complex under phosphine-free conditions

The palladium-catalyzed cross-coupling reaction of vinyl heteroaromatic compounds with aryl bromides and heteroaryl bromides is described using air and moisture stable N,N′,N″,O-tetrafunctional Pd catalyst under phosphine-free conditions. As a result a variety of trans-1,2-disubstituted vinyl heterocycles were obtained in high to good yields.

Utilities of olefin derivatives

Compounds having an activity to enhance the expression of apoAI are provided. Compounds of formula (I): in which Ar1 and Ar2 are independently a phenyl, naphthyl, or monocyclic or bicyclic aromatic heterocyclic group, which may be optionally substituted; —X— is —N═CZ2-, —CY2═CZ2-, —CY2Y3—CHZ2-, —S—, —O—, or the like; Y1, Y2, Y3, Z1 and Z2 are independently a hydrogen, a halogen, a lower alkyl, a phenyl, or the like; Z1 and Z2 may be independently a linker group that may combine with Ar2 and Ar1 to form a condensed ring; m is 0 or 1, and n is 0 to 2; a prodrug thereof, a pharmaceutically acceptable salt or solvate of them; are disclosed.