17773-64-7Relevant articles and documents
Reactions of Hydrogen Chloride with 3-Methyl-1-butyne: Cycloaddition and Rearrangement Reactions via Vinyl Cations
Stammann, Guenter,Griesbaum, Karl
, p. 598 - 606 (2007/10/02)
3-Methyl-1-butyne was reacted with anhydrous hydrogen chloride in the liquid phase at ambient temperatures.A total of 12 products were identified: three monoadducts (4, 6, 9), three diadducts (5, 7, 10), one substitution product (8), as well as five cycloaddition products having cyclobutane structures (11-15).Model reactions provided evidence for the mode of formation of the reaction products.