177747-75-0Relevant academic research and scientific papers
"Syn-effect" in the conversion of (e)-α,β-unsaturated esters into the corresponding β,γ-unsaturated esters and aldehydes into silyl enol ethers
Guha, Samar Kumar,Shibayama, Atsushi,Abe, Daisuke,Sakaguchi, Maki,Ukaji, Yutaka,Inomata, Katsuhiko
, p. 2147 - 2157 (2004)
The stereochemistry in the conversion of (E)-α,β-unsaturated esters into the corresponding β,γ-unsaturated esters, and that in the conversion of aldehydes into the silyl enol ethers, were investigated. The Z/E ratios of the resulting β,γ-unsaturated ester
Continuous-flow generation of diazoesters and their direct use in S-H and P-H insertion reactions: Synthesis of α-sulfanyl, α-sulfonyl, and α-phosphono carboxylates
Bartrum, Hannah E.,Blakemore, David C.,Moody, Christopher J.,Hayes, Christopher J.
, p. 2276 - 2282 (2013/04/10)
The synthesis of α-sulfanyl, α-sulfonyl, and α-phosphono carboxylates has been achieved using a two-step procedure involving the in-flow generation of diazoesters from sulfonylhydrazones, via Bamford-Stevens elimination, and then subsequent S-H, sulfinate
