177779-88-3 Usage
Uses
Used in Coordination Chemistry:
2,2':6',2''-Terpyridine, 6,6'''-(1,3-phenylene)bisis used as a ligand in coordination chemistry for the synthesis of metal complexes. Its terpyridine moiety allows for the formation of stable complexes with various metal ions, making it a valuable component in the development of new coordination compounds with potential applications in catalysis, sensing, and materials science.
Used in Organic Synthesis:
In the field of organic synthesis, 2,2':6',2''-Terpyridine, 6,6'''-(1,3-phenylene)bisis used as a building block for the synthesis of complex organic molecules. Its bisphenyl moiety provides a structural framework that can be further functionalized or modified to create a wide range of organic compounds with diverse properties and applications.
Used in Polymer Chemistry:
2,2':6',2''-Terpyridine, 6,6'''-(1,3-phenylene)bisis also utilized in polymer chemistry as a monomer or a comonomer for the synthesis of polymers with specific properties. The incorporation of the terpyridine and bisphenyl moieties into polymer structures can lead to materials with unique characteristics, such as enhanced stability, improved conductivity, or tailored interactions with other molecules.
Used in Supramolecular Chemistry:
In supramolecular chemistry, 2,2':6',2''-Terpyridine, 6,6'''-(1,3-phenylene)bisis employed as a component in the construction of supramolecular assemblies. Its ability to form stable complexes with metal ions, combined with its structural features, makes it a promising candidate for the development of self-assembled systems with potential applications in drug delivery, sensing, and molecular recognition.
Used in Materials Science:
Check Digit Verification of cas no
The CAS Registry Mumber 177779-88-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,7,7,7 and 9 respectively; the second part has 2 digits, 8 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 177779-88:
(8*1)+(7*7)+(6*7)+(5*7)+(4*7)+(3*9)+(2*8)+(1*8)=213
213 % 10 = 3
So 177779-88-3 is a valid CAS Registry Number.
177779-88-3Relevant academic research and scientific papers
Ho, Paul Kwok-Keung,Peng, Shie-Ming,Wong, Kwok-Yin,Che, Chi-Ming
, p. 1829 - 1834 (1996)
New polypyridines [1,3-bis(2,2′:6′,2″-terpyridin-6-yl)benzene L1 and 1,3-bis[4-(4-tert-butylphenyl)-2,2′:6′,2″-terpyridin-6-yl) benzene] L2 were prepared. Their reactions with copper(II) acetate and silver(I) acetate gave [Cu2L12]4+, [Cu2L22]4+, [Ag2L12]2+ and [Ag2L22]2+ while [Ru2L2(terpy)2]4+ was obtained from [Ru(terpy)Cl3] (terpy = 2,2′:6′,2″-terpyridine) with L2. The complexes [Cu2L22][PF6] 4·6MeCN and [Ag2L22][PF6]·Me 2CO have been established by X-ray crystal analyses to have double helical structures. Electrospray mass spectrometry showed that the double helical [Cu2L22]4+ and [Ag2L12]2+ complexes and the single helical [Ru2L2(terpy)2]4+ complex are the only species present in solutions. All five complexes undergo reversible oxidations or reductions. Interestingly, the electrochemical data indicate substantial electronic coupling within the bimetallic double helical [M2L2]3+ (M = Cu or Ag, L = L1 and L2) but not the single helical [Ru2L2(terpy)2]4+ systems.
