177854-95-4Relevant academic research and scientific papers
Dihydric alcohol containing disulfide bond as well as preparation method and application thereof
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Paragraph 0065; 0072, (2021/03/31)
The invention relates to the technical field of dihydric alcohol, in particular to dihydric alcohol containing disulfide bonds as well as a preparation method and application thereof. The structure ofthe disulfide bond-containing dihydric alcohol is shown as a formula (1) as the specification; the preparation raw materials of the disulfide bond-containing dihydric alcohol comprise a compound shown as a formula (2) and peroxide, wherein the formula (2) is shown as the specification; in the process of preparing the dihydric alcohol containing the disulfide bond, cheap raw materials are adopted,no catalyst is used, a one-pot reaction is adopted, and the method is simple in process, convenient to operate and easy to implement; a micro-channel mixing reactor is adopted, so that excessive polyether byproducts are prevented from being generated, and the purity is improved; meanwhile, the problem of product purity caused by constructing disulfide bonds by using polysulfide is avoided. The disulfide bond-containing dihydric alcohol can be applied to the fields of polyester, polyurethane and other materials, and is used for improving the performance of the materials.
pH dependent hydrolysis of 2-hydroxypropyl methanethiolsulfonate
Mao, John,Watson, Carl F.,Dix, Marjorie E.
, p. 1896 - 1899 (2007/10/03)
The hydrolysis of 2-hydroxypropyl methanethiolsulfonate (HPMTS), an industrial water treatment microbicide, was investigated at 25°C and at three pH values (pH 5, 7, and 9). Radiolabeled (14C) HPMTS at a concentration of 100 mg/L was used to determine rate constants and to identify hydrolytic degradation products. The hydrolysis at all three pHs followed pseudo-first-order kinetics with rate constants of 5.8 × 10-4, 7.6 × 10-2, and 7.3. h-1 at pH 5, 7, and 9, respectively. Two major radiolabeled hydrolytic degradation products were observed at all three pH values and were identified to be bis(2-hydroxyisopropyl) disulfide and bis(2-hydroxypropyl) disulfide by particle beam LC/MS. On the basis of the observed degradation products, a hydrolytic degradation pathway for HPMTS using propylene epoxide as a reactive intermediate was postulated.
