177900-25-3

Basic information

• Product Name: (C₆H₅)2C₂(NNC(SCH₃)NN)2C₃H₂(CH₃)2Ni
• Synonyms: (C₆H₅)2C₂(NNC(SCH₃)NN)2C₃H₂(CH₃)2Ni
• CAS NO: 177900-25-3
• Molecular Weight: 535.319
• Mol File: 177900-25-3.mol

Chemical Properties

• CAS DataBase Reference: (C₆H₅)2C₂(NNC(SCH₃)NN)2C₃H₂(CH₃)2Ni(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₅)2C₂(NNC(SCH₃)NN)2C₃H₂(CH₃)2Ni(177900-25-3)
• EPA Substance Registry System: (C₆H₅)2C₂(NNC(SCH₃)NN)2C₃H₂(CH₃)2Ni(177900-25-3)

Safety Data

• Hazardous Substances Data: 177900-25-3(Hazardous Substances Data)

Upstream product

• 37839-01-3 1H(+)-S-methylisothiocarbonohydrazidium iodide 
• 134-81-6 benzil 
• 123-54-6 acetylacetone 

Relevant articles and documents

Template synthesis and a study of nickel(II) complexes with asymmetric 15-membered macrocyclic octaaza ligands based on S-alkylisothiocarbohydrazides and α- and β-diketones

Nickel(II) coordination compounds with asymmetric 15-membered macrocyclic octaaza ligands based on S-alkylisothiocarbohydrazides and α- and β-diketones (NiL) were obtained by template synthesis. The (5 : 6 : 5 : 7) succession of chelate rings was identified for the first time, although six types of linkage isomers are possible for the synthesized ligands. The formation of a certain NiL isomer is determined by the order in which the reagents are introduced in the reaction. The structure of the synthesized compounds was established by electron-impact mass spectrometry, IR and NMR spectroscopy, and X-ray diffraction techniques.