177906-18-2

Basic information

• Product Name: Benzene, 2-(ethenylsulfinyl)-1,3,5-trimethyl-, (R)-
• CAS NO: 177906-18-2
• Molecular Formula: C11H14OS
• Molecular Weight: 194.298
• Mol File: 177906-18-2.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 2-(ethenylsulfinyl)-1,3,5-trimethyl-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 2-(ethenylsulfinyl)-1,3,5-trimethyl-, (R)-(177906-18-2)
• EPA Substance Registry System: Benzene, 2-(ethenylsulfinyl)-1,3,5-trimethyl-, (R)-(177906-18-2)

Safety Data

• Hazardous Substances Data: 177906-18-2(Hazardous Substances Data)

Upstream product

• 1826-67-1 vinyl magnesium bromide 

Relevant articles and documents

Enantioselective additive pummerer-type reaction in chiral, non-racemic vinyl sulfoxides induced by O-silylated ketene acetal

Treatment of chiral, non-racemic vinyl sulfoxides with O-silylated ketene acetal in the presence of a catalytic amount of zinc chloride in tetrahydrofuran resulted in an enantioselective Pummerer-type reaction, affording a considerable yield of the corresponding enantiomerically enriched methyl 4-siloxy-4-sulfenylbutyrate in 78-82% ee.