177971-45-8

Upstream product

• 109-79-5 n-butanethiol 
• 214214-05-8 4-tert-Butyl-2,6-bis[(2,2'',6,6''-tetramethyl-m-terphenyl-2'-yl)methyl]phenylsulfenyl iodide 
• 406675-53-4 C₅₆H₅₇NO₂S 
• 110-91-8 morpholine 
• 877465-02-6 dithioformic acid 4-tert-butyl-2,6-bis-(2,6,2'',6''-tetramethyl-[1,1';3',1'']terphenyl-2'-ylmethyl)-phenyl ester 
• 406675-51-2 S-nitroso-4-t-butyl-2,6-bis[(2,2,6,6-tetramethyl-m-terphenyl-2'-yl)methyl]benzenethiol 
• 186256-53-1 4-tert-butyl-2,6-bis[(2,2'',6,6''-tetramethyl-m-terphenyl-2'-yl)methyl]benzenesulfenic acid 
• 177971-43-6 (4-tert-butyl-2,6-bis[(2,2'',6,6''-tetramethyl-m-terphenyl-2'-yl)-methyl]phenyl)Br 

Downstream Products

• 406675-51-2 S-nitroso-4-t-butyl-2,6-bis[(2,2,6,6-tetramethyl-m-terphenyl-2'-yl)methyl]benzenethiol 
• 214214-05-8 4-tert-Butyl-2,6-bis[(2,2'',6,6''-tetramethyl-m-terphenyl-2'-yl)methyl]phenylsulfenyl iodide 
• 186256-53-1 4-tert-butyl-2,6-bis[(2,2'',6,6''-tetramethyl-m-terphenyl-2'-yl)methyl]benzenesulfenic acid 

Relevant academic research and scientific papers

Deprotonation of aryl methanedithioate by lithium amides: Formation of lithium arylthio(thioxo)methanide having unique reactivity

Deprotonation of aryl methanedithioate 5 bearing a bowl-type bulky subsituent with lithium tetramethylpiperidide at low temperature gave organolithium species 9 which was in equilibrium with a dimeric species 10; 9 extruded C=S at higher temperatures, thu

Synthesis of highly reactive organosulfur compounds

Application of novel bowl-type and dendrimer-type steric protection groups to the first synthesis of stable aromatic S-nitrosothiols is described. These compounds showed remarkable thermal stability whereas they easily reacted with appropriate reagents. X-ray crystallographic analysis established their structures, where the C-S-N-O linkage adopts only the syn conformation. Synthesis of a stable sulfenic acid by taking advantage of the bowl-type substituent is also delineated.

The First Stable Aromatic S-Nitrosothiol: Synthesis, Structure and Reactivity

The first stable aromatic S-nitrosothiol, S-nitroso-4-t-butyl-2,6-bis[(2,2",6,6"-tetramethyl-m-terphenyl-2'-yl)methyl]benzenethiol, was synthesized by the nitrosation of the corresponding thiol and the structure was established by X-ray crystallography. Its oxidation and reactions with some nucleophiles were carried out.

Syntheses and structures of stable sulfenyl iodides bearing novel bowl-type and dendrimer-type substituents

Arenesulfenyl iodides with unprecedented stability were synthesized by iodine oxidation of the corresponding arenethiols bearing bowl-type and dendrimer-type substituents. X-ray crystallographic analysis established their monomeric structures.

Synthesis and crystal structure of an arenesulfenyl iodide with unprecedented stability

An arenesulfenyl iodide with unprecedented stability was synthesized by oxidation of a thiol bearing a novel bowl-type substituent with iodine, whose monomeric structure was determined by X-ray crystallographic analysis.

Synthesis and structure of a novel molecular bowl with an all-carbon and acyclic framework

A novel all-carbon molecular bowl 2 where the central functionality is surrounded by two rigid tetramethyl-m-terphenyl units was designed. Bromide 3 was readily synthesized by copper(I)-catalyzed coupling reaction between 4 and 5. X-ray crystallographic analysis established that 3 has a bowl-shaped structure although it is an acyclic molecule. Butyl sulfide 6 and thiol 8 were synthesized via lithiation of 3.