17806-86-9Relevant academic research and scientific papers
Steric Effects in Heteroboranes. III. 1-Ph-2-Me-1,2-closo-C2B10H10
Mcgrath, Thomas D.,Welch, Alan J.
, p. 646 - 649 (1995)
The crystallographically determined structure of 2-methyl-1-phenyl-1,2-dicarba-closo-dodecaborane(12), C9H18B10, is reported.The 12-vertex polyhedron is relatively undistorted although the phenyl substituent is twisted by ca 73 deg from its electronically preferred orientation by steric pressure from the methyl group, resulting in a C-C(cage) separation of 1.695 (5) Angstroem.
Light-promoted copper-catalyzed cage C-Arylation of: O-carboranes: facile synthesis of 1-Aryl-o-carboranes and o-carborane-fused cyclics
Lu, Zhenpin,Ni, Hangcheng,Xie, Zuowei
supporting information, p. 14944 - 14948 (2021/09/04)
Light-promoted, copper catalyzed cage C-H arylation of o-carboranes with aryl halides has been achieved, leading to the facile synthesis of a variety of 1-Aryl-o-carboranes and o-carborane-fused cyclics. This method has the following features: (1) using o
Photoarylation of Iodocarboranes with Unactivated (Hetero)Arenes: Facile Synthesis of 1,2-[(Hetero)Aryl]n-o-Carboranes (n=1,2) and o-Carborane-Fused Cyclics
Ni, Hangcheng,Qiu, Zaozao,Xie, Zuowei
supporting information, p. 712 - 716 (2017/01/14)
Photoarylation of iodocarboranes with unactivated arenes/heteroarenes at room temperature has been achieved, for the first time, thus leading to the facile synthesis of a large variety of cage carbon mono(hetero)arylated and di(hetero)arylated o-carboranes. This work represents a clean, efficient, transition-metal-free, and cheap synthesis of functionalized carboranes, which has significant advantages over the known methods.
Nickel-catalyzed cross-coupling reactions of o-carboranyl with aryl iodides: Facile synthesis of 1-aryl-o-carboranes and 1,2-diaryl-o-carboranes
Tang, Cen,Xie, Zuowei
supporting information, p. 7662 - 7665 (2015/06/25)
A nickel-catalyzed arylation at the carbon center of o-carborane cages has been developed, thus leading to the preparation of a series of 1-aryl-o-carboranes and 1,2-diaryl-o-carboranes in high yields upon isolation. This method represents the first examp
Reactions of Lithium and Magnesium Derivatives of o-Carboranes with Carbonyl Compounds
Kazantsev,Butyaikin,Kazantsev,Otrashchenkov
, p. 83 - 86 (2007/10/03)
Reactions of lithium and magnesium derivatives of o-carboranes with methyl formate, ethyl formate, dimethylformamide, and some other compounds containing a formyl group were studied. Some regular trends and specific features of these reactions were revealed.
