17814-57-2Relevant academic research and scientific papers
Synthese de germyl perfluoroalcanes sulfonates. Quelques aspects de leur reactivite en tant qu'agent de germylation
Castany,Lavayssiere,Dousse
, p. 781 - 801 (2008/10/09)
Trifluoromethanesulfonates of germanium(IV) and (II) have been synthesized by reacting triflic acid or silver triflate with several functional organogermanes. Their characterization by 1H, 13C, 19F NMR, IR and mass spectrometry is described. The reactivity with neutral or charged nucleophiles (protic and aprotic) has also been studied. In the case of neutral nucleophiles, the reaction appeared to be a good method for germylation of enolizable ketones and esters.
SILYL- AND GERMYLMERCURIALS IN ORGANIC SYNTHESIS. A NEW ROUTE TO O-SILYLATED AND O-GERMYLATED ENOLATES
Kruglaya, O. A.,Belousova, L. I.,Gendin, D. V.,Kalikhman, I. D.,Vyazankin, N. S.
, p. 69 - 80 (2007/10/02)
The exchange reaction of α-mercurated ketones with bis(triethylsilyl)- (I) and bis(triethylgermyl)mercury (II) leads to the formation of the corresponding triethylsilyl and triethylgermyl enol ethers.O-Silylated and O-germylated enolates derived from keto
