178159-27-8

Upstream product

• 39789-20-3 cis-1,2-bis(trimethylsilyloxy)cyclohexane 
• 157611-54-6 1-Phenyl-3-((R)-toluene-4-sulfinyl)-propan-2-one 
• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 101-41-7 benzeneacetic acid methyl ester 

Downstream Products

• 178159-34-7 (1S,2R)-2-[(E)-1-Benzyl-2-((R)-toluene-4-sulfinyl)-vinyloxy]-cyclohexanol 
• 178232-53-6 (1R,2S)-2-[(E)-2-Phenyl-1-((R)-toluene-4-sulfinylmethyl)-vinyloxy]-cyclohexanol 
• 178232-52-5 (1S,2R)-2-[(E)-2-Phenyl-1-((R)-toluene-4-sulfinylmethyl)-vinyloxy]-cyclohexanol 

Relevant academic research and scientific papers

Novel asymmetric desymmetrization of meso-1,2-diols via diastereoselective β-elimination of chiral α-arylsulfinyl acetals

Enantioselective desymmetrization of meso-1,2-diols was accomplished via diastereoselective C-O bond fission of acetals derived from various optically active β-ketosulfoxides with high diastereoselectivities. The substituent at the γ-position of the β-ketosulfoxide plays an important role in this cleavage.