17822-23-0Relevant academic research and scientific papers
The impact of the heteroatom in a five-membered ring on the photophysical properties of difluoroborates
Grabarz, Anna M.,J?drzejewska, Beata,Skotnicka, Agnieszka,Murugan, N. Arul,Patalas, Filip,Bartkowiak, Wojciech,Jacquemin, Denis,O?mia?owski, Borys
, (2019)
A series of novel BF2 complexes, bearing a five-membered heterocyclic ring (with X = NMe, O, and S), were synthesized and characterized with a focus on the influence of atom exchange on the photophysical properties of both unsubstituted and dim
Benzothiazole-enamide-based BF2 complexes: Luminophores exhibiting aggregation-induced emission, tunable emission and highly efficient solid-state emission
Liu, Qingsong,Wang, Xiaoqing,Yan, Hui,Wu, Yanping,Li, Zhenyu,Gong, Shuwen,Liu, Peng,Liu, Zhipeng
supporting information, p. 2953 - 2959 (2015/03/30)
A series of benzothiazole-enamide-based boron difluoride complexes (Borebt1-6) were synthesized and characterized. These new luminophores were demonstrated to possess aggregation-induced emission, tunable, substituent-dependent emission profiles and large Stokes shift in solution. In the solid state, Borebt1-6 exhibited intense emission with high quantum yields of 0.21-0.37. The photophysical properties and AIE characteristics of these compounds were rationalized through X-ray crystal analysis, electrochemical studies and theoretical calculations. Furthermore, Borebt3-6 were capable of sensing acidic gas by reversible changes of emission, which may potentially serve as solid-state fluorescent sensors for acidic vapors. This journal is
