178388-67-5

Upstream product

• 17580-24-4 1,5-bis(phenylethynyl)naphthalene 

Downstream Products

• 247232-98-0 C₆H₅C₂Co₂(CO)4((C₆H₅)2PCH₂P(C₆H₅)2)C₁₀H₆(CCC₆H₅) 
• 247233-15-4 C₆H₅C₂Co₂(CO)6(C₁₀H₆)C₂(C₆H₅)Co₂(CO)4((C₆H₅)2PCH₂P(C₆H₅)2) 
• 247233-09-6 (C₆H₅C₂Co₂(CO)4(P(OCH₃)3)2)2C₁₀H₆ 

Relevant academic research and scientific papers

Electronic interactions in diyne Co2(CO)6 complexes

Electrochemical criteria are used to evaluate the electronic interaction between redox centres in the π-conjugated diyne complexes (RCSC[Co2(CO)6]C=EC[Co2(CO)6]R] and (RC=C[Co2(CO)6]-(S)-C=C[Co2(CO)6]R] (R = Ph,Fc) where the aromatic spacer S is phenyl, napthalene or anthracene. Voltammetry at microelectrode, differential pulse techniques and low temperature measurements are used to obviate the chemical complications following the primary redox process. A mechanism is proposed which successfully simulates the electrochemical data.