178388-68-6Relevant academic research and scientific papers
Electronic communication in [Co2(CO)6]2-diyne and [Co2(CO)4(dppm)]2-diyne complexes
Osella, Domenico,Milone, Luciano,Nervi, Carlo,Ravera, Mauro
, p. 1473 - 1477 (2008/10/08)
The electrochemical behaviour of the [Co2(CO)6]2(μ-R-C=C-L-C=C-R) and [Co2(CO)4(dppm)]2(μ-R-C=C-L-C=C-R) series is reported. Qualitative evidence suggests that both through-space and throug
Electronic interactions in diyne Co2(CO)6 complexes
Duffy, Noel,McAdam, John,Nervi, Carlo,Osella, Domenico,Ravera, Mauro,Robinson, Brian,Simpson, Jim
, p. 99 - 104 (2008/10/08)
Electrochemical criteria are used to evaluate the electronic interaction between redox centres in the π-conjugated diyne complexes (RCSC[Co2(CO)6]C=EC[Co2(CO)6]R] and (RC=C[Co2(CO)6]-(S)-C=C[Co2(CO)6]R] (R = Ph,Fc) where the aromatic spacer S is phenyl, napthalene or anthracene. Voltammetry at microelectrode, differential pulse techniques and low temperature measurements are used to obviate the chemical complications following the primary redox process. A mechanism is proposed which successfully simulates the electrochemical data.
