178394-33-7Relevant academic research and scientific papers
Mechanism of silver-mediated di-tert-butylsilylene transfer from a silacyclopropane to an alkene
Driver, Tom G.,Woerpel
, p. 9993 - 10002 (2007/10/03)
Kinetic studies of the reactions of cyclohexene silacyclopropane 1 and monosubstituted alkenes in the presence of 5 mol % of (Ph3P) 2AgOTf suggested a possible mechanism for silver-mediated di-tert-butylsilylene transfer. The kinetic
Mechanism of di-tert-butylsilylene transfer from a silacyclopropane to an alkene
Driver, Tom G.,Woerpel
, p. 10659 - 10663 (2007/10/03)
Kinetic and thermodynamic studies of the reactions of cyclohexene silacyclopropane 1 and monosubstituted alkenes suggested a possible mechanism for di-tert-butylsilylene transfer. The kinetic order in cyclohexene silacyclopropane 1 and cyclohexene were de
Metal-catalyzed silacyclopropanation of mono- and disubstituted alkenes
Cirakovic, Jelena,Driver, Tom G.,Woerpel
, p. 9370 - 9371 (2007/10/03)
As an alternative to the strongly reducing conditions necessary for the formation of silacyclopropanes, silylene transfer was developed as a mild, functional group tolerant method of silacyclopropanation. Complex silacyclopropanes were formed from functio
Siliranes: Formation, isonitrile insertions, and thermal rearrangements
Kroke, Edwin,Willms, Stefan,Weidenbruch, Manfred,Saak, Wolfgang,Pohl, Siegfried,Marsmann, Heinrich
, p. 3675 - 3678 (2007/10/03)
The siliranes 7-10 and 22 as well as the vinylsiliranes 14-16, 20, and 21 are prepared by [1 + 2]-cycloadditions of silylene 2 with alkenes and dienes. The first isonitrile insertion products, the silacyclobutanimines 26-28 were synthesized and the structure of 28 was determined by X-ray crystallography. Upon thermolysis 20-22 rearranged quantitatively to furnish the compounds 29-32.
