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Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate, also known as Rh(nbd)2(OTf), is an organometallic compound consisting of a rhodium(I) center coordinated to two norbornadiene ligands and a trifluoromethanesulfonate counterion. It is an orange solid and is widely used as a catalyst in various chemical reactions due to its unique properties.

178397-71-2

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178397-71-2 Usage

Uses

Used in Chemical Synthesis:
Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate is used as a reactant for metalation via C-C bond cleavage, which is a crucial step in the synthesis of various organic compounds. This process allows for the selective functionalization of organic molecules, leading to the formation of new carbon-carbon or carbon-heteroatom bonds.
Used in Catalyst Production:
Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate is used as a precursor in the synthesis of rhodium/ph-binepine catalysts. These catalysts are highly effective in various asymmetric hydrogenation reactions, which are essential for the production of enantiomerically pure compounds with potential applications in the pharmaceutical, agrochemical, and fine chemical industries.
Used as a Catalyst in Enantioselective Hydrogenation:
Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate is used as a catalyst for enantioselective hydrogenation, a reaction that plays a vital role in the synthesis of chiral compounds. These chiral compounds are often found in biologically active molecules, such as pharmaceuticals and agrochemicals, where the enantiomeric purity of the product is crucial for their desired biological activity.

Check Digit Verification of cas no

The CAS Registry Mumber 178397-71-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,8,3,9 and 7 respectively; the second part has 2 digits, 7 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 178397-71:
(8*1)+(7*7)+(6*8)+(5*3)+(4*9)+(3*7)+(2*7)+(1*1)=192
192 % 10 = 2
So 178397-71-2 is a valid CAS Registry Number.

178397-71-2 Well-known Company Product Price

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  • Aldrich

  • (701610)  Bis(norbornadiene)rhodium(I)trifluoromethanesulfonate  97%

  • 178397-71-2

  • 701610-250MG

  • 1,620.45CNY

  • Detail

  • Aldrich

  • (701610)  Bis(norbornadiene)rhodium(I)trifluoromethanesulfonate  97%

  • 178397-71-2

  • 701610-1G

  • 5,403.06CNY

  • Detail

178397-71-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name bicyclo[2.2.1]hepta-2,5-diene,rhodium,trifluoromethanesulfonate

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:178397-71-2 SDS

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