178557-28-3

Basic information

• Product Name: (R)-4-tert-Butyl-2-[(R)-2-(bis(1-phenyl)-phosphino)ferrocen-1-yl]oxazoline
• Synonyms: (R)-4-tert-Butyl-2-[(R)-2-(bis(1-phenyl)-phosphino)ferrocen-1-yl]oxazoline
• CAS NO: 178557-28-3
• Molecular Formula: C32H39FeNOP
• Molecular Weight: 540.476921
• Mol File: 178557-28-3.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (R)-4-tert-Butyl-2-[(R)-2-(bis(1-phenyl)-phosphino)ferrocen-1-yl]oxazoline(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-4-tert-Butyl-2-[(R)-2-(bis(1-phenyl)-phosphino)ferrocen-1-yl]oxazoline(178557-28-3)
• EPA Substance Registry System: (R)-4-tert-Butyl-2-[(R)-2-(bis(1-phenyl)-phosphino)ferrocen-1-yl]oxazoline(178557-28-3)

Safety Data

• Hazardous Substances Data: 178557-28-3(Hazardous Substances Data)

Usage

Chemical Properties

Dark yellow powder

Upstream product

• 1079-66-9 chloro-diphenylphosphine 

Relevant articles and documents

Enantioselective Palladium-Catalyzed Intramolecular α-Arylative Desymmetrization of 1,3-Diketones

An efficient enantioselective protocol has been reported to build highly oxygenated and densely substituted bicyclo[m.n.1] skeletons through intramolecular asymmetric α-arylative desymmetrization of 1,3-diketones. Employing Pd catalyst and FOXAP ligand, various bicyclo[m.n.1] skeleton with different size can be accessed with high enantio- and diastereoselectivities. Utilizing the present method as a key step, formal asymmetric total synthesis of the (-)-parvifoline has been demonstrated.